Ring-Inversion Barriers for the 3- and 4-Cyclohexenyl Radicals in Solution

DOI: 10.1021/jo00391a026

Source and publish data:

Journal of Organic Chemistry p. 3316 - 3319 (1987)

Update date:2022-08-06

Topics: Experimental Solution Barriers

Authors:

Berson, J. A.

Griller, D.

Owens, K.

Wayner, D. D. M.

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Article abstract of DOI:10.1021/jo00391a026

Ring-inversion barriers for the 3- and 4-cyclohexenyl radicals were investigated by an electron paramagnetic resonance (EPR) method and were found to be 7.0 +/- 0.9 and 2.4 +/- 0.5 kcal mol^-1 in fluid solution.The inversion motions and the magn

Full text of DOI:10.1021/jo00391a026

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