Organic Letters p. 5196 - 5199 (2010)
Update date:2022-08-04
Topics:
Toya, Hiroki
Okano, Kentaro
Takasu, Kiyosei
Ihara, Masataka
Takahashi, Atsushi
Tanaka, Haruo
Tokuyama, Hidetoshi
The enantioselective total synthesis of (-)- and (+)-petrosin is described. The union of two key segments was executed by Suzuki-Miyaura coupling. The quinolizidine rings were stereoselectively constructed via a diastereoselective Mannich reaction and an aza-Michael reaction. The 16-membered ring was constructed by ring-closing metathesis with the second-generation Grubbs catalyst.
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Doi:10.1021/jm1007566
(2010)Doi:10.1002/anie.201003125
(2010)Doi:10.1016/j.tetlet.2010.08.066
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(2014)Doi:10.1039/c0dt00259c
(2010)Doi:10.1021/om100611p
(2010)
