Tetrahedron p. 4227 - 4234 (1989)
Update date:2022-08-03
Topics:
Cecchi, P.
Pizzabiocca, A.
Renzi,G.
Chini, M.
Crotti, P.
et al.
Comparative analysisof the ratio of the isomeric monomethyl ethers of 1-arylcyclohexane-1,2-diols formed in the gas-phase and solvolytic acid-induced methanolysis of several 1-arylcyclohexene oxides indicates the intrinsic electronic factors detrminimg the regio- and stereochemical course of the nucleophilic attack, related to the partial degree of carbocationic character at the reaction centre in the substitution transition state.
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