Oxidation of 2,2,3,3-Tetramethyl-1,4-diphenyl-5,6-dithiabicyclohexane and Its Oxidation Products: An Important Role of 1,3-Transannular Interaction in the 1,3-Dithietane Part

DOI: 10.1246/bcsj.65.3343

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3343 - 3349 (1992)

Update date:2022-08-03

Topics:

Authors:

Ishii, Akihiko

Ding, Meng-Xin

Maeda, Kiyoto

Nakayama, Juzo

Hoshino, Masamatsu

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Article abstract of DOI:10.1246/bcsj.65.3343

Oxidation of 2,2,3,3-tetramethyl-1,4-diphenyl-5,6-dithiabicyclo<2.1.1>hexane with m-chloroperbenzoic acid gives two isomeric endo- (4a) and exo-sulfoxides (4b), three S,S'-dioxides (endo, exo-5a, exo, exo-5b, and endo, endo-5c), and an S,S,S'-tioxide (6).

Full text of DOI:10.1246/bcsj.65.3343

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