ENANTIOSPECIFIC SYNTHESIS OF (+)-(R)-1-PHENYL-3-METHYL-1,2,4,5-TETRAHYDROBENZAZEPINE FROM (+)-(S)-N-METHYL-1-PHENYL ETHANOLAMINE (HALOSTACHINE) via ARENE CHROMIUM TRICARBONYL METHODOLOGY

DOI: 10.1016/S0040-4039(00)99447-4

Source and publish data:

Tetrahedron Letters p. 3581 - 3584 (1989)

Update date:2022-08-04

Topics:

Authors:

Coote, Steven J.

Davies, Stephen G.

Middlemiss, David

Naylor, Alan

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Article abstract of DOI:10.1016/S0040-4039(00)99447-4

Acid promoted cyclisation of homochiral (R)-N-(3,4-dimethoxyphenethyl) halostachine chromium tricarbonyl is stereospecific, proceeding with retention of configuration, to afford, after decomplexation, homochiral (+)-(R)-1-phenyl-3-methyl-1,2,4,5-tatrahydr

Full text of DOI:10.1016/S0040-4039(00)99447-4

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