
Synlett p. 2411 - 2414 (2010)
Update date:2022-07-29
Topics:
Novak, Tibor
Mucsi, Zoltán
Balázs, Barbara
Keresztély, László
Blaskó, Gábor
Nyerges, Miklós
Novel 2-benzazepino[4,5-a]naphthalene derivatives were synthesised efficiently via 1,7-electrocyclisation of nonstabilised azomethine ylides derived from 1-aryl- or 1-alkenyl-naphthalene-2-carbaldehyde derivatives. In some cases, surprisingly, pyrrole derivatives were isolated. A mechanism for the formation of the pyrrole byproduct is proposed. Georg Thieme Verlag Stuttgart New York.
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Doi:10.1246/bcsj.20100141
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