On the reactivity of rhodium(I) complexes with κp -coordinated γ-phosphino-functionalized propyl phenyl sulfide ligands: Routes to cyclic rhodium complexes with Κc,ΚP - And Κp,ΚS -coordinated ligands as well as bis(diphenylphosphino)methanide ligands

DOI: 10.1021/om100878n

Source and publish data:

Organometallics p. 6749 - 6762 (2010)

Update date:2022-08-03

Topics:

Authors:

Block, Michael

Kluge, Tim

Bette, Martin

Schmidt, Juergen

Steinborn, Dirk

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Article abstract of DOI:10.1021/om100878n

Reactions of dinuclear μ-chlorido rhodium(I) complexes [(RhL ₂)₂(μ-Cl)₂] (L₂ = cycloocta-1,5-diene, cod, 3; L₂ = PλP: Ph₂PCH ₂PPh₂, dppm, 4a; Ph₂P(CH_2<

Full text of DOI:10.1021/om100878n

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Product name:[Rh(CO)(Cy2PCH2CH2CH2SPh-κP)(dppp-κ2P,P')](1+)

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