Studies Dealing with the Alkylation--Rearrangement Reaction of Some Phenylthio-Substituted Allylic Sulfones

DOI: 10.1021/jo00290a029

Source and publish data:

Journal of Organic Chemistry p. 955 - 964 (1990)

Update date:2022-09-26

Topics:

Authors:

Padwa, Albert

Bullock, William H.

Dyszlewski, Andrew D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00290a029

A series of 2-(phenylthio)-3-(phenylsulfonyl)alkenes are easily metalated with n-butyllithium, and the resulting carbanion is regioselectively alkylated by alkyl halides in the α-position to give β,γ-unsaturated sulfones in high yield.These substituted ph

Full text of DOI:10.1021/jo00290a029

Products guided by the article

Product name:3-(phenylsulfonyl)-2-(ethylthio)-1-propene

Cas No:125914-23-0

R&D Labs maybe for 125914-23-0

changsha chenjin chemical technology co.,LtD(expird)

Contact:86-731-84451263

Address:Room 201/217-218, 101 Jingyuan Electronic Technology Co.,Ltd. Testing Center, No.69, Lufeng Road, High-tech Development Zone, Changsha, China
xuri chemicals co., ltd

Contact:86-516-66656369

Address:The west road of Huaihai, Xuzhou, China
HANWAYS CHEMPHARM CO.,LIMITED

website:http://www.hanwayschem.com

Contact:+86-18502787239(whatsapp)-

Address:18-1-802, Green Garden, Jianghan District, Wuhan 430023, China
Shanghai Hohance Chemical Co., ltd

Contact:13914753421

Address:Fl.5；Bld. 70, Lane 1500; Xinfei Road
Suqian Ruixing Chemical Co., Ltd.

Contact:+86-527-80805666（总机）;84836008(销售)

Address:3 Jingsilu, Zone north, Hubin Xincheng Development Park, Suqian, China

Relevant to this article

Syntheses, spectral and crystallographic studies of novel monometallic Co(II) and Zn(II) complexes with phenyl-(5-pyridin-4-yl[1,3,4]thiadiazol-2-yl)- amine

Doi:10.1016/j.molstruc.2010.09.012
(2010)
Novel 2-(R-phenyl)amino-3-(2-methylpropenyl)-[1,4]-naphthoquinones: Synthesis, characterization, electrochemical behavior and antitumor activity

Doi:10.1590/s0103-50532010000100024
(2010)
Synthesis of benzotriazine and aryltriazene derivatives starting from 2-azidobenzonitrile derivatives

Doi:10.1002/ejoc.201000328
(2010)
Practical diastereoselective synthesis and scale-up study of (+)-2-((1r,2r,3r,5s)-2-amino-6,6-dimethylbicyclo[3.1.1]hept-3-yl)ethanol: A key intermediate of the novel prostaglandin d₂ receptor antagonist s-5751

Doi:10.1021/op9001092
(2009)
Novel insights into the mode of action of vasorelaxant synthetic polyoxygenated chalcones

Doi:10.3390/ijms21051609
(2020)
Expanded ring N-heterocyclic carbenes: A comparative study of ring size in palladium (0) catalysed Mizoroki-Heck coupling

Doi:10.1039/c1dt10596e
(2011)

Article Doi