Studies Dealing with the Alkylation--Rearrangement Reaction of Some Phenylthio-Substituted Allylic Sulfones

DOI: 10.1021/jo00290a029

Source and publish data:

Journal of Organic Chemistry p. 955 - 964 (1990)

Update date:2022-09-26

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Authors:

Padwa, Albert

Bullock, William H.

Dyszlewski, Andrew D.

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Article abstract of DOI:10.1021/jo00290a029

A series of 2-(phenylthio)-3-(phenylsulfonyl)alkenes are easily metalated with n-butyllithium, and the resulting carbanion is regioselectively alkylated by alkyl halides in the α-position to give β,γ-unsaturated sulfones in high yield.These substituted ph

Full text of DOI:10.1021/jo00290a029

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