
Journal of Organometallic Chemistry p. C13 - C17 (1989)
Update date:2022-07-30
Topics:
Herrmann, Wolfgang A.
Ladwig, Monika
Kiprof, Paul
Riede, Juergen
The first examples of arylmetal oxides of general formula (?-aryl)MOx have been synthesized, for M=Re.The compounds (?-aryl)ReO3 (3) are obtained in a simple, ostensibly general route by treatment of dirhenium heptoxide with the corresponding arylzinc compound Zn(?-aryl)2.As side product, the zinc perrhenate Zn(thf)2(ReO4)2 formed and precipitated as insoluble material from the solution. (Mesityltrioxo)rhenium(VII) was characterized by an X-ray diffraction study (pyramidal geometry).
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