A TOTAL SYNTHESIS OF A STAGE SPECIFIC EMBRYONIC ANTIGEN-3 (SSEA-3), GLOBOPENTAOSYL CERAMIDE, IV3GalGb4Cer. USE OF 2,4,6-TRIMETHYLBENZOYL GROUP AS A STEREOCONTROLLING AUXILIARY

DOI: 10.1016/S0040-4039(00)80845-X

Source and publish data:

Tetrahedron Letters p. 5681 - 5684 (1988)

Update date:2022-09-26

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Authors:

Nunomura, Shigeki

Ogawa, Tomoya

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Article abstract of DOI:10.1016/S0040-4039(00)80845-X

A first total synthesis of a SSEA-3, Galβ1-3GalNAcβ1-3Galα1-4Galβ1-4Glcβ1-3Cer, was achieved in an efficient way by using a key glycopentaosyl glycosyl donor that carried a stereocontrolling auxiliary at O-2a.

Full text of DOI:10.1016/S0040-4039(00)80845-X

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