Steric Control of Epoxidation by Carbamate and Amide Groups. Evidence for the Carbonyl-Directed Epoxidation

DOI: 10.1021/jo00297a047

Source and publish data:

Journal of Organic Chemistry p. 3236 - 3243 (1990)

Update date:2022-07-29

Topics:

Authors:

Kocovsky, Pavel

Stary, Ivo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00297a047

Allylic and homoallylic carbamoyloxy groups show a pronounced syn stereodirecting effect on peroxy acid epoxidation similar to that of hydroxy groups (5 -> 8).Carbonyl oxygen of the ambident carbamoyloxy group has been found to be responsible for this ste

Full text of DOI:10.1021/jo00297a047

Products guided by the article

Product name:Benzyl-carbamic acid (3S,4R,5S,8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[4,5]cyclopenta[a]phenanthren-3-yl ester

Cas No:125995-55-3

R&D Labs maybe for 125995-55-3

ANGCHEN BRIGHTCHEM CO., LTD

website:http://www.angchenchem.com

Contact:+86-510-88302099 82327577

Address:Rm. 404/405, Floor 4th, No. 983 FengXiang Road, Wuxi, China
Chengdu Sino-Strong Pharmaceutical Co.,Ltd.

website:http://www.sino-strong.com.cn

Contact:+86-28-82666753

Address:459 West haike road,Cross-straits technological industry park, Wenjiang district,Chengdu, P.R.China
Hangzhou Showland Technology Co., Ltd.

Contact:86-571-88920516

Address:ROOM2118,NO.553,WENSAN ROAD,HANGZHOU,CHINA
Tosta Enterprise Co., Ltd.

Contact:+86-134-5286-9121

Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,
Jinan Decheng Hemu Medical Technology Co.，Ltd.

Contact:+86-531-68650525

Address:NO.554 Zhengfeng Road High-new Technology Development Zone

Relevant to this article

Hydroxylated Metabolites of Loratadine: An Example of Conformational Diastereomers Due to Atropisomerism

Doi:10.1021/jo00297a065
(1990)
Design, crystal structures and enhanced frequency-upconverted lasing efficiencies of a new series of dyes from hybrid of inorganic polymers and organic chromophores

Doi:10.1039/b914656c
(2009)
PCN- and PCS-pincer palladium complexes as tandem catalysts in homoallylation reactions

Doi:10.1002/adsc.201000204
(2010)
Solvent-promoted highly selective dehydrogenation of tetrahydroisoquinolines without catalyst and hydrogen acceptor

Doi:10.1016/j.tetlet.2016.01.008
(2016)
Synthesis of a selectively protected trisaccharide building block of the capsular polysaccharide of streptococcus pneumoniae types 6A and 6B

Doi:10.1016/0008-6215(89)85090-6
(1989)
Asymmetric synthesis of Pachastrissamine (Jaspine B) and its diastereomers via η³-allylpalladium intermediates

Doi:10.1039/c0ob00643b
(2011)

Article Doi