Pd-catalyzed cross-coupling of α-(acyloxy)-tri-n -butylstannanes with alkenyl, aryl, and heteroaryl electrophiles

Article abstract of DOI:10.1021/ol102863u

Racemic and scalemic α-(acyloxy)-tri-n-butylstannanes undergo Pd-catalyzed cross-couplings with alkenyl/aryl/heteroaryl iodides, bromides, and triflates in moderate to good yields in THF at 45 °C. Simple aryl iodides and unprotected aza-arenes, two classe