Oxidative addition of carbon-oxygen and carbon-nitrogen double bonds to WCl2(PMePh2)4. Synthesis of tungsten metallaoxirane and tungsten oxo- and imido-alkylidene complexes

DOI: 10.1021/ja00162a034

Source and publish data:

Journal of the American Chemical Society p. 2298 - 2308 (1990)

Update date:2022-08-04

Topics:

Authors:

Bryan, Jeffrey C.

Mayer, James M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00162a034

WCl₂L₄ (1, L = PMePh₂) reacts rapidly with a variety of ketones and aldehydes to form bis(η²-ketone) or bis(η²-aldehyde) complexes WCl₂(η²-O=CRR′)₂L₂ (2, 3)

Full text of DOI:10.1021/ja00162a034

Products guided by the article

Product name:tungsten bis(η2-cyclobutanone)(Cl)2(PMePh2)2

Cas No:126018-13-1

R&D Labs maybe for 126018-13-1

Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
Shandong united-rising pharmaceutical cooperation.,ltd.

Contact:008653187965009

Address:171No., Jing5 Road, Shizhong District, Jinan, China
Wuhan Chemchemical Co., Ltd.(expird)

Contact:15973022782

Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.
Hebei DaPeng Pharm & Chem Co., Ltd.

Contact:86-317-7298678,0576-88861898 88861908

Address:West Songmen Village, East Songmen Town, Wuqiao, Cangzhou, Hebei ,China
Kraeber & Co GmbH

Contact:+49-4101-3053-0

Address:Waldhofstrasse 14 ,25474 Ellerbek Germany

Relevant to this article

Amide-Substituted Titanocenes in Hydrogen-Atom Transfer Catalysis

Doi:10.1002/anie.201509548
(2016)
Visible-Light Driven Selective C-N Bond Scission in anti-Bimane-Like Derivatives

Doi:10.1021/acs.orglett.1c01376
(2021)
The Use of Triphosgene in Preparation of N-Carboxy-α-amino Acid Anhydrides

Doi:10.1021/jo00035a044
(1992)
Homologous size-extension of hybrid vanadate capsules - Solid state structures, solution stability and surface deposition

Doi:10.1039/c3cc48541b
(2014)
Synthesis of the WXYZA' domain of maitotoxin

Doi:10.1021/ja109533y
(2011)
Imidazoliophosphines are true N-heterocyclic carbene (NHC)-phosphenium adducts

Doi:10.1002/chem.201001721
(2010)

Article Doi