Oxidative addition of carbon-oxygen and carbon-nitrogen double bonds to WCl2(PMePh2)4. Synthesis of tungsten metallaoxirane and tungsten oxo- and imido-alkylidene complexes

DOI: 10.1021/ja00162a034

Source and publish data:

Journal of the American Chemical Society p. 2298 - 2308 (1990)

Update date:2022-08-04

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Authors:

Bryan, Jeffrey C.

Mayer, James M.

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Article abstract of DOI:10.1021/ja00162a034

WCl₂L₄ (1, L = PMePh₂) reacts rapidly with a variety of ketones and aldehydes to form bis(η²-ketone) or bis(η²-aldehyde) complexes WCl₂(η²-O=CRR′)₂L₂ (2, 3)

Full text of DOI:10.1021/ja00162a034

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Product name:tungsten bis(η2-cyclobutanone)(Cl)2(PMePh2)2

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