DECARBOXYLATION OF α-AMINO ACIDS BY PYRUVIC ACID AND ITS DERIVATIVES. EVIDENCE FOR AZOMETHINE YLIDES IN IN VITRO ANALOGUES OF PYRUVOYL ENZYMIC PROCESSES

DOI: 10.1016/S0040-4039(00)99139-1

Source and publish data:

Tetrahedron Letters p. 2841 - 2844 (1989)

Update date:2022-08-05

Topics:

Authors:

Grigg, Ronald

Henderson, Deirdre

Hudson, Andrew J.

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Article abstract of DOI:10.1016/S0040-4039(00)99139-1

Reaction of α-amino acids with pyruvic acid, ethyl pyruvate or pyruvamide in hot DMF results in imine formation followed by decarboxylation to generate azomethine ylides stereospecifically.The azomethine ylides undergo stereospecific cycloaddition to N-me

Full text of DOI:10.1016/S0040-4039(00)99139-1

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