Photochemical 1,3-Oxygen-to-Carbon Migrations. An Efficient, High-Yield Route to Protected Spirodienones

DOI: 10.1021/jo00295a003

Source and publish data:

Journal of Organic Chemistry p. 2272 - 2274 (1990)

Update date:2022-09-26

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Authors:

Wang, Shaopeng

Callinam, Andrew

Swenton, John S.

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Article abstract of DOI:10.1021/jo00295a003

Irradiation of ethylene ketals of spiro p-quinol vinyl ethers in the presence of piperylene affords protected 2,5-cyclohexadienones in high quantum and chemical yields via a 1,3-oxygen-to-carbon migration.

Full text of DOI:10.1021/jo00295a003

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