STEREOSELECTIVE ADDITION OF α-CHLORO ALLYLIC CHROMIUM REAGENTS TO ALDEHYDES

DOI: 10.1016/S0040-4039(00)99368-7

Source and publish data:

Tetrahedron Letters p. 4389 - 4392 (1989)

Update date:2022-08-05

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Authors:

Takai, Kazuhiko

Kataoka, Yasutaka

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/S0040-4039(00)99368-7

Treatment of a solution of 1,1-dichloro-2-butene and benzaldehyde with CrCl2 in THF-DMF at 25 deg C for 1 h gave threo-(Z)-4-chloro-2-methyl-1-phenyl-3-buten-1-ol in 96percent yield under high stereocontrol.

Full text of DOI:10.1016/S0040-4039(00)99368-7

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Product name:(1R,2R)-2-((Z)-2-Chloro-vinyl)-1-phenyl-pentan-1-ol

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