Russian Chemical Bulletin p. 543 - 544 (1996)
Update date:2022-07-29
Topics:
Krasnov
Koroleva
Rusinov
Reactions of diastereomeric dialkyl N-phthaloyl-4-haloglutamates with para-anisidine were studied at high pressure, and an additional confirmation of the exact SN2 mechanism of the reactions was obtained. Quantitative parameters of the relative reactivity of the diastereomers were found in various solvents, which made it possible to perform the desired synthesis of products of diastereomeric substitution.
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