
Tetrahedron Letters p. 4219 - 4222 (1989)
Update date:2022-08-06
Topics:
Bannwarth, Willi
Kueng, Erich
Bis(allyloxy)(diisopropylamino)phosphine is a new phosphinylating agent which can be employed for an effective phosphorylation of hydroxy functions after activation by tetrazole followed by an oxidation step.The allyl protecting groups are removed afterwards with Pd(O)P(C6H5)3)4 leading to the corresponding phophorylated substrate.
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