BIS(ALLYLOXY)(DIISOPROPYLAMINO)PHOSPHINE AS A NEW PHOSPHINYLATION REAGENT FOR THE PHOSPHORYLATION OF HYDROXY FUNCTIONS

DOI: 10.1016/S0040-4039(01)80694-8

Source and publish data:

Tetrahedron Letters p. 4219 - 4222 (1989)

Update date:2022-08-06

Topics:

Authors:

Bannwarth, Willi

Kueng, Erich

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Article abstract of DOI:10.1016/S0040-4039(01)80694-8

Bis(allyloxy)(diisopropylamino)phosphine is a new phosphinylating agent which can be employed for an effective phosphorylation of hydroxy functions after activation by tetrazole followed by an oxidation step.The allyl protecting groups are removed afterwards with Pd(O)P(C6H5)3)4 leading to the corresponding phophorylated substrate.

Full text of DOI:10.1016/S0040-4039(01)80694-8

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