Tetrahedron p. 5979 - 5986 (1989)
Update date:2022-08-05
Topics:
Ali, Sk. Asrof
Khan, Javaid H.
Wazeer, Mohammed I. M.
Perzanowski, Herman P.
A comparative study of the stereochemical behaviour of the 1,3-dipolar cycloaddition of a series of 1,2-disubstituted alkenes with 1-pyrroline 1-oxide (1) and 2,3,4,5-tetrahydropyridine 1-oxide (2) has been carried out.Both the nitrones exhibit very similar stereochemical properties.Rate constants for the cycloaddition of these nitrones to several disubstituted alkenes have been determined at 36 C by 1H n.m.r. spectroscopy.It is found that the nitrone 1 reacts slower than 2 due to the presence of bond eclipsing strain in the transition state involving 1.
View MoreShijiazhuang City Xiehe Pharmaceutical Co., Ltd
Contact:+86-311-80817929
Address:Shangzhuang,Shijiazhuang,China
Shanghai united Scientific Co.,Ltd.
Contact:+86-21-53535353
Address:28F No.900 huaihai Road Shanghai China
Hangzhou Eastbiopharm Co.,Ltd.
Contact:+86-571-88931780
Address:Hangzhou,China
Contact:+86-571-86025531 / 86024803
Address:1218-24 Guangyin Mansion,42 Fengqi East Road
RongCheng K&S Chemical Co.,Ltd
Contact:0631-7336369
Address:rongcheng ,shandong province china
Doi:10.1039/c3ob27177c
(2013)Doi:10.1016/j.inoche.2013.01.014
(2013)Doi:10.1016/j.cclet.2013.01.041
(2013)Doi:10.1055/s-0032-1316829
(2013)Doi:10.1016/j.poly.2012.07.028
(2013)Doi:10.1021/jo400077m
(2013)
