Tetrahedron p. 6203 - 6210 (1989)
Update date:2022-08-03
Topics:
Alexakis, A.
Jachiet, D.
Toupet, L.
Substituted dienyl cyclohexanols, obtained through opening of cyclohexene oxide by dienyl aluminium reagents, are easily esterified with acryloyl, crotonyl or methacryloyl chloride or with maleic anhydride.These esters undergo a completely stereoselective Lewis acid catalyzed Diels-Alder reaction.The obtained product were characterized by X-ray crystallography.
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