NOVEL ENTRY TO THE TROPANE SYSTEM BY REACTION OF RHODIUM(II) ACETATE STABILIZED VINYLCARBENOIDS WITH PYRROLES

DOI: 10.1016/S0040-4039(01)80766-8

Source and publish data:

Tetrahedron Letters p. 4653 - 4656 (1989)

Update date:2022-08-02

Topics:

Authors:

Davies, Huw M. L.

Young, Wendy B.

Smith, H. David

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Article abstract of DOI:10.1016/S0040-4039(01)80766-8

Rhodium(II) acetate catalyzed decomposition of vinyldiazomethanes in the presence of N-alkoxycarbonylpyrroles provides a direct entry to the skeleton of tropane alkaloids.Similar reactions with N-alkylpyrroles result in the formation of alkylation products.

Full text of DOI:10.1016/S0040-4039(01)80766-8

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