Journal of Organic Chemistry p. 2958 - 2965 (1993)
Update date:2022-08-04
Topics: Stereoselective
Harada, Toshiro
Katsuhira, Takeshi
Hattori, Kazuhiro
Oku, Akira
Lithium trialkylzincates react efficiently with 1,1-dibromocyclopropanes 5 to give the corresponding alkylation products 7 nonstereoselectively.The reaction proceeds through a 1,2-alkyl migration of the intermediately formed zincate carbenoid 3 in an inve
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