Stereoselective Carbon-Carbon Bond-Forming Reaction of 1,1-Dibromocyclopropanes via 1-Halocyclopropylzincates

DOI: 10.1021/jo00063a010

Source and publish data:

Journal of Organic Chemistry p. 2958 - 2965 (1993)

Update date:2022-08-04

Topics: Stereoselective

Authors:

Harada, Toshiro

Katsuhira, Takeshi

Hattori, Kazuhiro

Oku, Akira

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Article abstract of DOI:10.1021/jo00063a010

Lithium trialkylzincates react efficiently with 1,1-dibromocyclopropanes 5 to give the corresponding alkylation products 7 nonstereoselectively.The reaction proceeds through a 1,2-alkyl migration of the intermediately formed zincate carbenoid 3 in an inve

Full text of DOI:10.1021/jo00063a010

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