Tetrahedron Letters p. 6023 - 6026 (1989)
Update date:2022-08-04
Topics:
Boubia
Mioskowski
Manna
Falck
The title arsonium ylide reacts with aldehydes to give exclusively α-thiophenoxyepoxides in THF and phenylthioenol ethers in THF/HMPA. The former adducts are readily transformed to α-thiophenoxy carbonyls and the latter to one-carbon homologated aldehydes.
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Doi:10.1002/anie.201607177
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