
Organometallics p. 1970 - 1972 (1990)
Update date:2022-08-03
Topics:
Gogan, Niall J.
De Silva, Sheila I.
A series of (aroylcyclopentadienyl)rhenium tricarbonyls ((η5-RC6H4COC5H 4)Re(CO)3, R = H, o-CH3, p-CH3, p-OCH3, o-F, p-Cl) and their Cr(CO)3 ((η6-arene)Cr(CO)3) complexes have been prepared and characterized and studied by IR and 1H NMR spectroscopy. The carbonyl stretching frequencies of the Re(CO)3 group and the cyclopentadienyl proton resonances indicate π-electron withdrawal through the ligand system by the Cr(CO)3 group.
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