Journal of the Chemical Society. Chemical communications p. 1608 - 1610 (1989)
Update date:2022-07-30
Topics:
Graziano, M. Liliana
Iesce, M. Rosaria
Cermola, Flavio
Giordano, Federico
Scarparti, Rachele
The carbonyl oxide (1), derived from the 2,3,7-trioxabicyclo<2.2.1>heptene (3) by thermal rearrangement, yields, as major products, methyl 1,2-dioxolane-4-carboxylate (8) and the novel tricyclic biperoxide (4) (whose structure was established by X-ray diffraction), by reaction with methyl acrylate and the acrylate (3) respectively, whereas it yields 5-ethoxy-1,2-dioxolane (9) with ethyl vinyl ether.
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