Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1869 - 1873 (1989)
Update date:2022-08-02
Topics:
Zhdankina, G. M.
Kryshtal', G. V.
Serebryakov, E. P.
Yanovskaya, L. A.
The reactions of citral with acetone cyanohydrin and secondary amines (diethylamine, piperidine, morpholine, and N-methylaniline) to give 2-substituted amino-4,8-dimethyl-3,7-nonadienoic acid nitriles have been examined.Possible pathways for these reactions are discussed.The thermolysis of 2-diethylamino-4,8-dimethyl-3,7-nonadienoic acid nitrile has been examined in solution, to give irreversibly 3-cyano-1-diethylamino-3,7-dimethyl-1,6-octadiene, this reaction proceeding faster in polar than in nonpolar solvents.
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