Journal of Organic Chemistry p. 3705 - 3707 (1990)
Update date:2022-07-29
Topics:
Borosky, Gabriela L.
Pierini, Adriana B.
Rossi, Roberto A.
1-Iodoadamantane (1) reacts under irradiation with the enolate ions of acetone (2), acetophenone (5a), and propiophenone (5b) to give adamantane and the substitution products in variable yields.The anion of nitromethane (7) does not react under irradiation with 1, but excellent yields of 1-adamantylnitromethane (8) are obtained in the photostimulated reaction of 1 and 7 in the presence of 2 or 5a (entrainment reactions).We suggest that 1-iodoadamantane reacts with these nucleophiles by the SRN1 mechanism of nucleophilic substitution.
View MoreDalian Synco Chemical Co., Ltd.
Contact:+86-411-83635150
Address:Rm 1004, 24, Tangshan Street, Dalian
jintan yufan Medicine Raw materials Co.,Ltd.(expird)
Contact:86-519-82808282
Address:6th,Jincheng Huangzhuang
Chengdu D-Innovation Pharmaceutical Co., Ltd
Contact:86-28-85105536
Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
HANGZHOU FOREWIN PHARMA CO., LTD
Contact:+86-571-89053961
Address:hangzhou
Hangzhou Donglou Bio-nutrient Co., Ltd.
Contact:+86-571-82225795,13967112289
Address:Louta Town, Xiaoshan,Hangzhou,Zhejiang
Doi:10.1021/jo00250a010
(1988)Doi:10.1021/ja00231a047
(1988)Doi:10.1246/cl.2009.208
(2009)Doi:10.1021/jo01213a006
(1939)Doi:10.1016/S0008-6215(00)90880-2
(1987)Doi:10.1021/ja00224a021
(1988)
