Journal of Organic Chemistry p. 3705 - 3707 (1990)
Update date:2022-07-29
Topics:
Borosky, Gabriela L.
Pierini, Adriana B.
Rossi, Roberto A.
1-Iodoadamantane (1) reacts under irradiation with the enolate ions of acetone (2), acetophenone (5a), and propiophenone (5b) to give adamantane and the substitution products in variable yields.The anion of nitromethane (7) does not react under irradiation with 1, but excellent yields of 1-adamantylnitromethane (8) are obtained in the photostimulated reaction of 1 and 7 in the presence of 2 or 5a (entrainment reactions).We suggest that 1-iodoadamantane reacts with these nucleophiles by the SRN1 mechanism of nucleophilic substitution.
View MoreSuzhou BEC Fine Chemicals Co., Ltd.
website:http://www.bek.com.cn
Contact:0512-68095917 18913193865
Address:6, Jin Shan Road, Suzhou New District, 215011 China Suzhou Nations Pharmaceutical Innovation Center Inside
Jiangxi Dongbang Pharmaceutical Co., Ltd.
Contact:+86-795-4433603, 4433388
Address:Fengxin Industrial Park, Fengxin County, Jiangxi Province, P.R.C
Changzhou Welton Chemical Co., Ltd,
Contact:0086-519-85910828,85920537,85912897
Address:No.8 Jinlong Road, Binjiang Park, Changzhou, Jiangsu, China.
Contact:+ 86 512 52491118
Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China
QINGDAO HONG JIN CHEMICAL CO.,LTD.
website:http://www.hongjinchem.com
Contact:+86-532-83657313
Address:2ND Building, 8 Shangqing Road, Qingdao, Shandong Province, China.
Doi:10.1021/jo00250a010
(1988)Doi:10.1021/ja00231a047
(1988)Doi:10.1246/cl.2009.208
(2009)Doi:10.1021/jo01213a006
(1939)Doi:10.1016/S0008-6215(00)90880-2
(1987)Doi:10.1021/ja00224a021
(1988)
