Journal of Organic Chemistry p. 3705 - 3707 (1990)
Update date:2022-07-29
Topics:
Borosky, Gabriela L.
Pierini, Adriana B.
Rossi, Roberto A.
1-Iodoadamantane (1) reacts under irradiation with the enolate ions of acetone (2), acetophenone (5a), and propiophenone (5b) to give adamantane and the substitution products in variable yields.The anion of nitromethane (7) does not react under irradiation with 1, but excellent yields of 1-adamantylnitromethane (8) are obtained in the photostimulated reaction of 1 and 7 in the presence of 2 or 5a (entrainment reactions).We suggest that 1-iodoadamantane reacts with these nucleophiles by the SRN1 mechanism of nucleophilic substitution.
View MoreRongCheng K&S Chemical Co.,Ltd
Contact:0631-7336369
Address:rongcheng ,shandong province china
Hangzhou Haiqiang Chemical Co.,Ltd.
Contact:+86-571-86960370
Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
Contact:+86-731-84427351
Address:154 JIANXIANG SOUTH ROAD
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD
Contact:29-63685658 63685359
Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD
Contact:86-21-60560171
Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
Doi:10.1021/jo00250a010
(1988)Doi:10.1021/ja00231a047
(1988)Doi:10.1246/cl.2009.208
(2009)Doi:10.1021/jo01213a006
(1939)Doi:10.1016/S0008-6215(00)90880-2
(1987)Doi:10.1021/ja00224a021
(1988)
