
Journal of Organic Chemistry p. 3442 - 3444 (1990)
Update date:2022-08-05
Topics:
Bachi, Mario D.
Denenmark, Daniella
(Tri-n-butyltin)thioimidoyl radicals of type 6, which were efficiently generated by treatment of alk-3-enyl- and alk-4-enylisothiocyanates with tri-n-butyltin hydride and AIBN, underwent exo cyclization to give, after hydrolysis, the corresponding γ- or δ-thiolactams in good to excellent yields.
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