Synthesis and reactivity of nitro sugar-derived silyl nitronates

DOI: 10.1016/S0040-4039(01)93326-X

Source and publish data:

Tetrahedron Letters p. 6143 - 6146 (1989)

Update date:2022-08-04

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Authors:

Martin Martin

Khamis Khamis

Rao Rao

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Article abstract of DOI:10.1016/S0040-4039(01)93326-X

Silyl nitronates are readily generated from carbohydrates containing a nitromethyl group; these nitronates participate in F^--catalyzed nitroaldol reactions with aldehydes provided that the nucleophilic carbon atom is sufficiently remote from th

Full text of DOI:10.1016/S0040-4039(01)93326-X

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