CpRu-catalyzed O-H insertion and condensation reactions of α-diazocarbonyl compounds

DOI: 10.1021/ol2000815

Source and publish data:

Organic Letters p. 1394 - 1397 (2011)

Update date:2022-08-03

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Authors:

Austeri, Martina

Rix, Diane

Zeghida, Walid

Lacour, Jerome

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Article abstract of DOI:10.1021/ol2000815

[CpRu(CH₃CN)₃][PF₆] and diimine ligands catalyze together the decomposition of α-diazocarbonyl compounds leading to O-H insertion and condensation reactions. In comparison with Rh(II) and Cu(I) complexes, the CpRu catalysts produce rapid and often more selective reactions. Promising enantioselectivities are obtained in dioxole syntheses.

Full text of DOI:10.1021/ol2000815

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