SYNTHESIS OF 12-HYDROPEROXYEICOSATETRAENOIC ACID (12-HPETE). ON THE STEROCHEMISTRY IN THE CONVERSION OF 12(S)-HETE TO 12-HPETE

DOI: 10.1016/S0040-4039(00)99133-0

Source and publish data:

Tetrahedron Letters p. 2817 - 2820 (1989)

Update date:2022-09-26

Topics:

Authors:

Nagata, Ryu

Kawakami, Masayuki

Matsuura, Teruo

Saito, Isao

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Article abstract of DOI:10.1016/S0040-4039(00)99133-0

12(S)-hydroxyeicosatetraenoic acid methyl ester 1 was synthesized. 1 was converted to phosphite 17 which upon treatment with hydrogen peroxide afforded the corresponding hydroperoxide 18 (12-HPETE methyl ester) with partially retained configuration.

Full text of DOI:10.1016/S0040-4039(00)99133-0

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