Asymmetric Catalysis by Vitamin B12: The Isomerization of Achiral Aziridines to Optically Active Allylic Amines

DOI: 10.1002/hlca.19930760719

Source and publish data:

Helvetica Chimica Acta p. 2602 - 2615 (1993)

Update date:2022-08-03

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Authors:

Zhang, Zhong da

Scheffold, Rolf

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Article abstract of DOI:10.1002/hlca.19930760719

Achiral N-acylaziridines are isomerized to optically active N-acyl-allylamines in ee's of up to 95percent by catalytic amounts of cob(I)alamin in MeOH.

Full text of DOI:10.1002/hlca.19930760719

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