Asymmetric Catalysis by Vitamin B12: The Isomerization of Achiral Aziridines to Optically Active Allylic Amines

DOI: 10.1002/hlca.19930760719

Source and publish data:

Helvetica Chimica Acta p. 2602 - 2615 (1993)

Update date:2022-08-03

Topics:

Authors:

Zhang, Zhong da

Scheffold, Rolf

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19930760719

Achiral N-acylaziridines are isomerized to optically active N-acyl-allylamines in ee's of up to 95percent by catalytic amounts of cob(I)alamin in MeOH.

Full text of DOI:10.1002/hlca.19930760719

Products guided by the article

Product name:N-(cyclopent-2-en-1-yl)-N-methylbenzamide

Cas No:127310-74-1

R&D Labs maybe for 127310-74-1

zhejiang huangyan wanfeng pharm chem co.ltd

Contact:+86-576- 84160728

Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China
Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C
ChangZhou XiaQing Chemical Co., Ltd.

Contact:+86-519-88721665

Address:3# Hengluo Road, Henglin Town, Changzhou City, Jiangsu Province，China
Xinyanhe Pharmatech Co.,Ltd

Contact:+86-519-8525-2752

Address:Changzhou
Nanjing Capatue Chemical Co., Ltd

Contact:+86-25-86371192 +86-025-85720158

Address:No.20 Jiangjun Avenue, Jiangning Economic & Technical Development Zone

Relevant to this article

The stereoselective synthesis of (Z)-HFC=CFZnI and stereospecific preparation of (E)-1,2-difluorostyrenes from (Z)-HFC=CFZnI via an unusual Pd(PPh₃)₄-Cu(I)Br co-catalysis approach or (Z)-HFC=CFSnBu₃

Doi:10.1016/j.jfluchem.2010.11.008
(2011)
A new synthesis of pyrazoles through a Lewis acid catalyzed union of 3-ethoxycyclobutanones with monosubstituted hydrazines

Doi:10.1021/ol2002682
(2011)
Small molecule agonists of the orphan nuclear receptors steroidogenic factor-1 (SF-1, NR5A1) and liver receptor homologue-1 (LRH-1, NR5A2)

Doi:10.1021/jm1014296
(2011)
A general synthetic strategy for the design of new BODIPY fluorophores based on pyrroles with polycondensed aromatic and metallocene substituents

Doi:10.1002/chem.201003242
(2011)
Intramolecular alkylations of aromatic compounds, XXVII: Synthesis of 3,4-dihydro-1'-methylspiro [naphthalene-1(2H),3'-piperidine]

Doi:10.1002/ardp.19903230105
(1990)
Stereochemical control in microbial reduction. 12. (S)-4-nitro-2-butanol as a source to synthesize natural products

Doi:10.1246/bcsj.63.91
(1990)

Article Doi