Synthesis of Oxepins via the Cope Rearrangement of cis-2,3-Divinyl Epoxides

DOI: 10.1021/jo00300a005

Source and publish data:

Journal of Organic Chemistry p. 3975 - 3977 (1990)

Update date:2022-08-05

Topics:

Authors:

Clark, David L.

Chou, Whe-Narn

White, James B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00300a005

The Cope rearrangement of cis-2,3-divinyl epoxides, which may be readily prepared from enynols, provides a flexible and efficient route to the oxepin ring system.

Full text of DOI:10.1021/jo00300a005

Products guided by the article

Product name:1-[3-((E)-2-Trimethylsilanyl-vinyl)-oxiranyl]-ethanone

Cas No:127332-61-0

R&D Labs maybe for 127332-61-0

ClickChem Technology Co., Limited

Contact:+86-0310-6519966/0531-52893837

Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
NINGBO YINLIANG FOREIGN TRADE CO., LTD.

Contact:+86-574-87834016 / 87898057

Address:23F NO.666JINYU ROAD,YINGZHOU DISTRICT,NINGBO.CHINA
JiangXi Hong Run Chemical Co., Ltd

Contact:+86-0791-88521351

Address:XingHuo industrial zone in YongXiu county
Weifang Jahwa Chemical Co.,Ltd

Contact:0086-536-8897731,8897730

Address:No.5166 East Dongfeng Street,Weifang,Shandong,China
waho int'l company

Contact:+86-579-85206992

Address:No 451 chouzhou north road ,room 1106 int'l business center , yiwu ,china

Relevant to this article

Synthesis, spectroscopic characterization and preliminary antimicrobial studies of Mn(II) and Cu(II) complexes of two thiolates; S,S'-(2,6- diaminopyridine-3,5-diyl) dibenzenecarbothioate (DBCT) and S-benzyl benzenecarbothioate (BBCT)

Doi:10.1155/2011/214870
(2011)
α-Sulfonyl radical initiated intramolecular tandem radical cyclization

Doi:10.1016/S0040-4039(01)93387-8
(1989)
Aqueous C-S cross-coupling: Synthesis of 2-iminobenzo-1,3-oxathioles via CuCl₂·H₂O-catalyzed tandem reaction of 2-iodophenols with isothiocyanates

Doi:10.1016/j.tetlet.2011.02.061
(2011)
Additional flexibility solves the leaving group problem in cyclodextrin acylation

Doi:10.1016/S0040-4039(00)94586-6
(1990)
Synthesis, characterization and microwave-assisted catalytic activity of novel benzimidazole salts bearing piperidine and morpholine moieties in Heck cross-coupling reactions

Doi:10.1002/aoc.1751
(2011)
Selective Cross-Coupling of (Hetero)aryl Halides with Ammonia to Produce Primary Arylamines using Pd-NHC Complexes

Doi:10.1021/acs.organomet.6b00830
(2017)

Article Doi