Addition of TMS-substituted oxiranyl anions to acylsilanes. A highly stereoselective approach to tetrasubstituted (Z)-β-hydroxy-α-TMS silyl enol ethers

DOI: 10.1021/ol200116f

Source and publish data:

Organic Letters p. 1440 - 1443 (2011)

Update date:2022-08-04

Topics:

Authors:

Song, Zhenlei

Kui, Leizhou

Sun, Xianwei

Li, Linjie

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Article abstract of DOI:10.1021/ol200116f

A highly stereoselective approach to novel tetrasubstituted (Z)-β-hydroxy-α-TMS silyl enol ethers is described. The reaction proceeds via a sequential addition/[1,2]-Brook rearrangement/epoxide-opening process of TMS-substituted oxiranyl anions with acyls

Full text of DOI:10.1021/ol200116f

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