Electronic and Steric Influences on Face Selection during the Oxy-Cope Rearrangement of an α-Allyl-α-vinylbenzyl Alcohol

DOI: 10.1021/jo00298a041

Source and publish data:

Journal of Organic Chemistry p. 3597 - 3602 (1990)

Update date:2022-08-04

Topics:

Authors:

Lin, Man-hua

Watson, William H.

Kashyap, Ram P.

Noble, W. J. le

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00298a041

The racemic RR,SS and RS,SR diastereomers of 5-(5-fluoroadamant-2-ylidene)-4-hydroxy-4-phenyl-1-pentene (1-F) have been synthesized.Their configurations have been determined by means of ¹³C NMR as well as by way of an X-ray diffraction study of

Full text of DOI:10.1021/jo00298a041

Products guided by the article

Product name:2-(benzoylmethylidene)-5-fluoroadamantane

Cas No:127491-79-6

R&D Labs maybe for 127491-79-6

Yancheng Smiling Imp & Exp Co., Ltd.

Contact:+86-515-83173586

Address:Rm1207, BLD#03, Phoenix Plaza, Juheng Road, Yancheng, Jiangsu, P.R. China
Hangzhou Donglou Bio-nutrient Co., Ltd.

Contact:+86-571-82225795,13967112289

Address:Louta Town, Xiaoshan,Hangzhou,Zhejiang
Nanjing Norris Pharm Technology Co., Ltd.

Contact:+86-13901585132

Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
Shandong Zhongcheng Barium Salt Co., Ltd

Contact:+86-15725732638

Address:No.29 baoxi road, hi-tech zone, zibo, shandong
Sinoway Industrial Co., Ltd.

website:http://www.china-sinoway.com

Contact:+86-592-5853819

Address:16/F,Huicheng Comm,Complex,No839 XiaHe Rd, Xiamen,China

Relevant to this article

Synthesis of 1,3-Dioxin-4-Ones and their use in synthesis.(1)) XVIII. Synthesis of azetidin-2-ones from 1,3-Dioxin-4-ones via 3-Hydroxycarboxamides

Doi:10.1248/cpb.37.2952
(1989)
New Synthesis of Natural Carotene Isorenieratene (φ,φ-Carotene) and its 3,3′-Dimethoxy Analogue

Doi:10.1002/hlca.200390273
(2003)
A NEW APPROACH TO CYCLIC NITRONES: APPLICATIONS TO THE SYNTHESIS OF α,α'-DISUBSTITUTED PIPERIDINES AND PYRROLIDINES

Doi:10.1016/S0040-4039(00)95065-2
(1985)
Mechanism of Molybdenum-Mediated Carbon Monoxide Deoxygenation and Coupling: Mono- and Dicarbyne Complexes Precede C-O Bond Cleavage and C-C Bond Formation

Doi:10.1021/jacs.6b10535
(2016)
Facile catalytic hydrosilylation of pyridines

Doi:10.1002/anie.201006135
(2011)
Intermolecular atom transfer radical addition to olefins mediated by oxidative quenching of photoredox catalysts

Doi:10.1021/ja108560e
(2011)

Article Doi