Tetrahedron Letters p. 7087 - 7090 (1989)
Update date:2022-08-05
Topics:
Horiguchi, Yoshiaki
Komatsu, Makoto
Kuwajima, Isao
The role of Me3SiCl to accelerate conjugate addition of organocopper reagents has been examined by comparison of the stereochemical results of reactions with 6- and 2,6-disubstituted cyclohexenones, and mechanism involving an initial coordination of the chlorosilane to enones has been proposed.
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Doi:10.1021/ol200313m
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