Tetrahedron Letters p. 6133 - 6134 (1989)
Update date:2022-09-26
Topics:
Lillya, C. Peter
Sassi, Thomas P.
Fluoride induced desilylation of a trimethylsilylcyclopropyl nitramine generated the first known nitramine α-anion, which was trapped in situ by electrophiles (H2O, D2O and CH3CHO).In contrast, a trimethylsilylmethyl nitramine gave a product resulting from elimination of the elements of trimethylsilyl nitrite under identical reaction conditions.
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