CHIRAL HANDLE-INDUCED DIASTEREOSELECTIVITY IN AN ORGANIC PHOTOREARRANGEMENT: SOLUTION VERSUS SOLID STATE RESULTS

DOI: 10.1016/S0040-4039(01)93321-0

Source and publish data:

Tetrahedron Letters p. 6125 - 6128 (1989)

Update date:2022-08-03

Topics:

Authors:

Chen, Jianxin

Garcia-Garibay, Miguel

Scheffer, John R.

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Article abstract of DOI:10.1016/S0040-4039(01)93321-0

The degree of asymmetric induction in the di-?-methane photorearrangement due to the presence of a remote chiral handle was found to vary with the nature and location of the chiral handle and with the medium in which the reaction was carried out.

Full text of DOI:10.1016/S0040-4039(01)93321-0

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