Synthesis of α,β-Unsaturated Thiocarboxylic Acid S-Esters via Horner-Emmons Olefination

Article abstract of DOI:10.1055/s-1990-26784

The title compounds are prepared by an efficient one-pot reaction using readily available phosphonates and S-alkyl carbonchloridothioates.The reaction is capable of variation in the phosphonate and especially in the carbonochloridothioate components.