Tetrahedron Letters p. 5713 - 5716 (1989)
Update date:2022-09-26
Topics:
Daly, Sharon M.
Armstrong, Robert W.
A 1,4'-C-disaccharide (20) containing an acetylenic linkage was synthesized from D-glucose via a homologation of a 4-ulose derivative (6a) followed by condensation with 2,3,4,6-tetrabenzyl pyranolactone.Subsequent reduction afforded isomerically pure β-C-disaccharide in good overall yield.
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