The Stereoselectivity of the Alkylation of the Dianion of Ethyl 2-Hydroxy-6-methylcyclohexanecarboxylates: Control of Stereochemistry at Three Adjacent Stereogenic Centers

DOI: 10.1002/hlca.19890720821

Source and publish data:

Helvetica Chimica Acta p. 1846 - 1851 (1989)

Update date:2022-07-29

Topics:

Authors:

Frater, Georg

Guenther, Wulf

Mueller, Urs

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19890720821

Yeast reduction of rac-ethyl 2-methyl-6-oxocyclohexanecarboxylate (rac-1) yielded selectively (+)-ethyl 2-hydroxy-6-methylcyclohexane carboxylate (+)-2 (Scheme 1) which has been alkylated with 5-iodo-2-methylbut-2-ene by the dianion method to furnish the

Full text of DOI:10.1002/hlca.19890720821

Products guided by the article

Product name:(+)-ethyl (1R,2S,6R)-2-hydroxy-6-methylcyclohexanecarboxylate

Cas No:127982-49-4

R&D Labs maybe for 127982-49-4

HANGZHOU EVC CHEMICAL CO.,LTD.(expird)

Contact:+86-571-88296056

Address:Room#3001,Zhejiang Chemical Market,No.10,Road Shenban,Hangzhou,Zhejiang,China
Shandong Ailitong New Material Co.,Ltd

Contact:+86-536-3226266

Address:zhongjia village, putong town , qingzhou city,Shandong Province,China
Tractus Company Limited

Contact:+852-8198 2399

Address:9E, Leapont Industrial Building, 18-28 Wo Liu Hang Road, Shatin, New Territories, Hong Kong
Nantong Baokai Chemical Co., Ltd (Hangzhou Baokai Bio-Chemicals Co.,Ltd.)

Contact:+86-513-83886111

Address:No. 68 Suzhou road ,Binjiang Fine Chemical Industrial Park , Beixin town, Qidong city ,Jiangsu province
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)

Contact:+86-571-87046953

Address:No. 37, Qingchun Road

Relevant to this article

Synthesis, structure, and photochemical reaction of 9,10-dihydro-9-silaanthracene derivatives carrying bulky substituents

Doi:10.1016/S0022-328X(00)00196-0
(2000)
Synthesis of 1,3-diaminated stereotriads via rearrangement of 1,4-diazaspiro[2.2]pentanes

Doi:10.1021/ol300269u
(2012)
Nucleophilic substitution of 6H-1,2-oxazines via azapyrylium ions

Doi:10.1055/s-1989-27428
(1989)
Determination and application of the excited-state substituent constants of pyridyl and substituted phenyl groups

Doi:10.1002/poc.4246
(2021)
Synthesis of a phosphorano-stabilized U(IV)-carbene via one-electron oxidation of a U(III)-Ylide adduct

Doi:10.1021/ja2001133
(2011)
Comparative analysis of the PET and ICT sensor properties of 1,8-naphthalimides containing aza-15-crown-5 ether moiety

Doi:10.1016/j.dyepig.2013.03.008
(2013)

Article Doi