Tetrahedron Letters p. 7357 - 7360 (1989)
Update date:2022-08-04
Topics:
Duplantier
Nantz
Roberts
Short
Somfai
Masamune
A strategy of triple asymmetric synthesis is illustrated to be effective for stereochemical control in fragment assembly, a task often encountered in convergent natural product synthesis. The stereochemical outcome of aldol reactions involving three chiral components supports a rule of approximate multiplicativity of facial selectivities intrinsic to the chiral reactants involved in each reaction.
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