Chemistry of Natural Compounds p. 28 - 33 (1990)
Update date:2022-08-03
Topics:
Koval'skaya, S. S.
Kozlov, N. G.
Novikova, M. G.
Shavyrin, S. V.
The transformation of 2α-hydroxy-2,6,6-trimethylbicyclo<3.1.1>heptan-3-one under the conditions of acid catalysis have been studied.It has been shown that this compound can be used for the synthesis of products of various structures: a bridged bicyclic lactone (1,8,8-trimethyl-2-oxabicyclo<3.2.1>octan-3-one), an aromatic compound (carvacrol), and nitrogen-containing derivatives of p-menthane such as 8-acylamino-p-menth-6-en-2-ones.The structures of the compounds synthesized were shown by the results of 1H and 13C NMR spectroscopies.
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Doi:10.1021/jo200154d
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