Ligandgesteuerte Produktbildung bei Umsetzung von 1,7-Octadien mit Phenylisocyanat an Nickel(0)

Article abstract of DOI:10.1016/0022-328X(90)87082-O

1,7-Octadiene and phenylisocyanate react with the (Lig)Ni⁰-system, depending on the ligand, to give differing products.Thus with tricyclohexylphosphane the reaction is accompanied by cyclization and (2-methylenecyclohexyl)acetanilide(V) is formed.On the other hand, reaction with the weakly basic tricyclohexylphosphite gives the acyclic nona-2,8-dienecarboxanilide (VI).