Tetrahedron Letters p. 1173 - 1176 (1990)
Update date:2022-08-05
Akasaka, Takeshi
Misawa, Yoshihisa
Ando, Wataru
Photosensitized oxygenation of adamantenylidenecyciopropanes (1) gave either the corresponding oxetanones (2a-c) or the cyclic ketones (4 and 5) depending on the substituent on the cyclopropane ring in addition to adamantanone. The results are rationalized in terms of initial formation of a perepoxide followed by that of a peroxyallyl intermediate.
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