ARYL-COUPLING VIA "AXIALLY PROSTEREOGENIC" LACTONES: FIRST TOTAL SYNTHESIS OF (+)-ANCISTROCLADISINE AND (OPTIONALLY) ITS ATROPISOMER

DOI: 10.1016/S0040-4039(01)93754-2

Source and publish data:

Tetrahedron Letters p. 5249 - 5252 (1989)

Update date:2022-08-05

Topics:

Authors:

Bringmann, Gerhard

Reuscher, Helmut

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)93754-2

The first total synthesis of the liana alkaloid ancistrocladisine (1a) and of its novel atropisomer 1b is reported.The required mixed aryl coupling is brought about, regiospecifically, by prefixation of the two molecular moieties by an ester-type auxiliar

Full text of DOI:10.1016/S0040-4039(01)93754-2

Products guided by the article

Product name:3-((S)-2-Benzylamino-propyl)-5-methoxy-phenol

Cas No:128350-29-8

R&D Labs maybe for 128350-29-8

Zhengzhou Xinlian Chemical Tech Co. ,Ltd

Contact:0371-65771781 021-52042910

Address:H Part, Building I, No. 700 Gonglu Road, Pudong New Area, Shanghai
Ji'nan Orgachem Pharmaceutical Co.,Ltd

Contact:+86-531-82687810

Address:Jinan
Jiangsu Taihu New Materials Holding Co., Ltd

Contact:+86-519-86160108

Address:Xueyan Town, Changzhou City, Jiangsu Province, 213169, China
Shanghai Yuking Water Soluble Material Tech Co., Ltd

Contact:86-21-68286299

Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
Changzhou Xuanming Chemical Co., Ltd.

Contact:86 0519 85525329

Address:China Town, Xinbei, Changzhou, Jiangsu Room 6019

Relevant to this article

Total synthesis of the polyether antibiotic ionomycin

Doi:10.1021/ja00169a042
(1990)
NUCLEOPHILIC CATALYSIS OF THE ADDITION OF TERTIARY PERFLUOROALKYL BROMIDES TO ALKENES AND ALKYNES

Doi:10.1007/BF00960371
(1990)
A novel and metal-free approach towards α-ketoamides using a TBHP/I₂-promoted tandem reaction of amines with β-diketones via C-C bond cleavage

Doi:10.1039/c2ra22116k
(2013)
Photoreactions of 4-(tribromomethyl)-4-methyl-2,5-cyclohexadienone and its derivatives with amines: Radical cyclization and ring expansion reactions promoted through photoinduced electron transfer processes

Doi:10.1021/jo990215v
(1999)
Carbohydrate liquid crystals: Synthesis and characterisation of the methyl-6-O-(n-acyl)-α-D-glucopyranosides

Doi:10.1016/j.chemphyslip.2010.11.007
(2011)
Glycosidase-Catalyzed Synthesis of Glycosyl Esters and Phenolic Glycosides of Aromatic Acids

Doi:10.1002/adsc.201900259
(2019)

Article Doi