ARYL-COUPLING VIA "AXIALLY PROSTEREOGENIC" LACTONES: FIRST TOTAL SYNTHESIS OF (+)-ANCISTROCLADISINE AND (OPTIONALLY) ITS ATROPISOMER

DOI: 10.1016/S0040-4039(01)93754-2

Source and publish data:

Tetrahedron Letters p. 5249 - 5252 (1989)

Update date:2022-08-05

Topics:

Authors:

Bringmann, Gerhard

Reuscher, Helmut

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Article abstract of DOI:10.1016/S0040-4039(01)93754-2

The first total synthesis of the liana alkaloid ancistrocladisine (1a) and of its novel atropisomer 1b is reported.The required mixed aryl coupling is brought about, regiospecifically, by prefixation of the two molecular moieties by an ester-type auxiliar

Full text of DOI:10.1016/S0040-4039(01)93754-2

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