ALDOL REACTIONS IN POLYPROPIONATE SYNTHESIS: HIGH ?-FACE SELECTIVITY OF ENOL BORINATES FROM α-CHIRAL METHYL AND ETHYL KETONES UNDER SUBSTRATE CONTROL.

DOI: 10.1016/S0040-4039(01)93440-9

Source and publish data:

Tetrahedron Letters p. 7121 - 7124 (1989)

Update date:2022-08-03

Topics:

Authors:

Paterson, Ian

Goodman, Jonathan M.

Isaka, Masahiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)93440-9

Use of (c-C6H11)2BCl in the anti-selective aldol reaction of the α-chiral ethylketone 2 leads to high stereoselectivity (>94percent) for the 1,2-anti-2,4-anti isomer 7.The related α-chiral methylketone aldol reaction, 8 <*> 9, proceeds with 84-93percent d

Full text of DOI:10.1016/S0040-4039(01)93440-9

Products guided by the article

Product name:(2S,5R)-1-benzyloxy-5-hydroxy-2-methyl-3-octanone

Cas No:128146-33-8

R&D Labs maybe for 128146-33-8

Shanghai Profirst Co., Ltd.

Contact:+86-21-38122007

Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
MiHecb Bio-Tech Co., Ltd.

Contact:+86-0592 5353131

Address:No.56 Guani Road Software Park 2,Siming District
Luojiang Chenming Biological Products Co

Contact:+86 15000297032

Address:GROUP NO.4, HE SHENG VILLAGE, PANLONG TOWN,
Jiangsu Taihu New Materials Holding Co., Ltd

Contact:+86-519-86160108

Address:Xueyan Town, Changzhou City, Jiangsu Province, 213169, China
Suzhou CarbonWell Pharma-Tech Co., Ltd

Contact:Tel: + 86 (0)512-8898-1216; + 86-18606258602

Address:2358 Changan Road, Wujiang Scientific Innovation Park, Wujiang, Jiangsu Province, P. R. China 215200

Relevant to this article

Analogues of DNA minor groove cross-linking agents incorporating aminoCBI, an amino derivative of the duocarmycins: Synthesis, cytotoxicity, and potential as payloads for antibody–drug conjugates

Doi:10.1016/j.bmc.2016.09.068
(2016)
Doi:10.1021/ja01167a090
(1950)
SYNTHETIC STUDY ON APLYSIATOXINS, HIGHLY INFLAMMATORY AGENTS AND TUMOR PROMOTERS. SYNTHESIS OF 3-DEOXYDEBROMOAPLYSIATOXIN

Doi:10.1016/S0040-4039(00)70661-7
(1989)
Catalytic asymmetric ring-opening of meso- aziridines with malonates under heterodinuclear rare earth metal Schiff base catalysis

Doi:10.1021/ja201492x
(2011)
Syntheses and characterizations of two zinc(II) metal-organic frameworks based on 1,4-naphthalenedicarboxylate and imidazole ligands

Doi:10.1002/zaac.201000315
(2011)
Scalable Electrochemical Transition-Metal-Free Dehydrogenative Cross-Coupling Amination Enabled Alkaloid Clausines Synthesis

Doi:10.1002/adsc.202000228
(2020)

Article Doi