Rearrangements of Bridgehead Bromides. A Direct Synthesis of epi-Modhephene

DOI: 10.1021/jo00307a001

Source and publish data:

Journal of Organic Chemistry p. 5423 - 5424 (1990)

Update date:2022-07-29

Topics:

Authors:

Kraus, George A.

Shi, Jianmin

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Article abstract of DOI:10.1021/jo00307a001

The reaction of nucleophiles with bridgehead bromides 3 and 4 affords rearrangement products resulting from addition of the nucleophile to the carbonyl group followed by ring contraction.This rearrangement has been employed in a direct synthesis of epi-mo

Full text of DOI:10.1021/jo00307a001

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Product name:(3aS,6aR)-6-Methyl-6a-(3-oxo-3-phenyl-propionyl)-2,3,4,6a-tetrahydro-1H-pentalene-3a-carboxylic acid methyl ester

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