INTERACTION OF VICINAL N-METHYL AND C2-ISOPROPYL SUBSTITUENTS IN 3-KETOPIPERIDINES: RING CONFIGURATION AND STEREOCHEMISTRY OF CARBONYL REACTIONS

DOI: 10.1007/BF00960345

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 776 - 781 (1990)

Update date:2022-07-29

Topics:

Authors:

Katvalyan, G. T.

Mistryukov, E. A.

Shashkov, A. S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00960345

The cis- and trans-1,5-dimethyl-2-isopropyl-3-piperidones were synthesized.Their configurations were determined using 1H and 13C NMR spectroscopy.The stereochemistry of the hydride and catalytic reduction of the resulting 3-piperidones was studied.

Full text of DOI:10.1007/BF00960345

Products guided by the article

Product name:cis-1,5-dimethyl-2-isopropyl-3-piperidol (a-epimer)

Cas No:128277-87-2

R&D Labs maybe for 128277-87-2

Tianjin Realet Chemical Technology Co.,Ltd.

website:http://www.realetchem.com

Contact:+86-022-58788819

Address:shuanggang industrial park
Zhengzhou Gecko Scientific Inc.

Contact:0371-88884176

Address:56 Hongzhuan Road, Zhengzhou, China
Zhejiang Genebest Pharmaceutical Co.,Ltd.

Contact:0086-571-63532866

Address:No.1 Jinboshi Rd Lishan Town Fuyang City Zhejiang Province China
SHIJIAZHUANG HENRYTE CHEMICALS CO,.LTD(expird)

Contact:+86-311-85208698 311-80837698

Address:NO.166, yuhua west road, SHIJIAZHUANG, China
Cangzhou Senary Chemical Science-tech Co., Ltd

Contact:+86-317-3563899, 3563699

Address:168 Jinde Road, Cangzhou, Hebei, China

Relevant to this article

Convergent synthesis of dolastatin 15 by solid phase coupling of an N- methylamino acid

Doi:10.1021/jo981055a
(1999)
Artificial model for cystathionine β-synthase: Efficient β-replacement reaction with thiols employing a novel pyridoxal model compound having an imidazole function

Doi:10.1016/S0040-4020(03)00666-5
(2003)
Stable ionic Rh(I,II,III) complexes ligated by an imidazolium-substituted phosphine with π-acceptor character: Synthesis, characterization, and application to hydroformylation

Doi:10.1021/om400171t
(2013)
Asymmetric allylic amination catalyzed by chiral ferrocenylphosphine-palladium complexes

Doi:10.1016/S0040-4039(00)88870-X
(1990)
Electrocatalytic Reduction of CO₂ to Methanol by Iron Tetradentate Phosphine Complex Through Amidation Strategy

Doi:10.1002/cssc.201802929
(2019)
Suppression of the skin response to alantolactone in alantolactone-sensitized guinea pigs treated with N-acetyl-L-cysteinyl-L-alanine methyl ester

Doi:10.1016/0223-5234(90)90017-W
(1990)

Article Doi