Chemical and Pharmaceutical Bulletin p. 1742 - 1749 (1992)
Update date:2022-08-02
Topics:
Nagaoka
Iwashima
Abe
Iguchi
Yamada
The stereoselective total synthesis of (+)-mayolide A (1) was achieved starting from D-mannitol via two crucial steps: stereoselective introduction of a two-carbon unit into the β-position of the butenolide 5 and repeated Claisen rearrangement to produce the side chain. The absolute structure of natural mayolide A from the Okinawan soft coral Sinularia mayi was determined as 2 by the present synthesis.
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(1992)Doi:10.1055/s-1992-26278
(1992)Doi:10.1002/ardp.19903230415
(1990)Doi:10.1021/jo051213f
(2005)Doi:10.1002/chem.201102446
(2011)Doi:10.1016/j.tetlet.2011.01.094
(2011)
